Luminescence characterization of BioGlass undoped and doped with europium and silver ions.

The objective of this study was to investigate the properties of BioGlass, with and without doping with europium and silver, with a specific focus on its potential application in thermoluminescent (TL) and optically stimulated luminescent (OSL) dosimetry. The structural and optical characteristics of the samples were also analyzed using techniques such as X-ray diffraction (XRD), optical absorption (OA), and fluorescence spectroscopy (FL). An XRD analysis confirmed the amorphous phase of the BioGlass. OA and FL spectra were obtained at room temperature, and characteristic bands of dopant ions were observed which confirmed the incorporation of the Eu3+ ions and silver nanoparticles Ag(NP) ion into the BioGlass. The OSL decay curves exhibited a characteristic exponential behavior, with a notable presence of fast and medium decay components; this suggests that the charge traps within the BioGlass samples possess a high photoionization cross section when exposed to blue LEDs, which are commonly used as the light source in OSL readers. Different TL glow peaks with varying shapes of the glow curve were observed when the dopant, the co-dopant, and the concentration of silver were altered in the samples. The TL kinetic parameters were determined, such as the order value, activation energy, and frequency factor, and the OSL parameters for the compound were also analyzed, including an exponential fit to the curves. Based on these initial results, we conclude that BioGlass has the potential for use in radiation dosimetry.

Investigation of dosimetric properties of CaSO4:Mn phosphor prepared using slow evaporation route.

The objective of this work was to investigate the luminescent properties of CaSO4:Mn synthesized by slow evaporation route. The crystalline structure, morphology, thermal and optical properties of the phosphors were characterized by X-ray diffraction analysis (XRD), Scanning electron microscopy (SEM), photoluminescence (PL) and thermogravimetric analysis (TGA). Moreover, using thermoluminescence (TL) and optically stimulated luminescence (OSL) techniques, the dosimetric properties of the phosphors, such as emission spectra, glow curve reproducibility, dose-response linearity, fading of the luminescent signal, variation of the TL intensity with the heating rate, OSL decay curves, correlation between TL and OSL emissions and minimum detectable dose (MDD) were comprehensively investigated. For dosimetric analyses, the samples were irradiated with doses from 169 mGy to 10 Gy. The emission band fits with the characteristic line of the Mn2+ emission features, ascribed to 6A1→4T1 transition. CaSO4:Mn pellets present a TL glow curve with a single typical peak centered around 494 nm, an OSL decay curve with predominance of a fast decay component, and a MDD on the order of mGy. The luminescent signals showed to be linear and reproducible in the studied dose range. The trapping centers located between 0.83 eV and 1.07 eV were revealed for different heating rates in the TL study. The high TL sensitivity of CaSO4:Mn was proven when comparing with commercially available dosimeters. The luminescent signals exhibit a smaller fading than described in the literature for CaSO4:Mn produced by other methods.